Novel Enantioselective Photocatalysis by Chiral, Helical Ruthenium(II) Complexes

DOI: 10.1039/c39930001423

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1423 - 1425 (1993)

Update date:2022-08-11

Topics:

Authors:

Ohkubo, Katsutoshi

Hamada, Taisuke

Ishida, Hitoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930001423

The enantioselective photoreduction of the helical substrates of rac- (acac- = acetylacetonato) and rac-^- (edta^4- = ethylenediaminetetraacetato) with the newly synthesized helical photocatalysts Δ- (or rac)-2+ -2,2'-bipyridine>, and Λ- (or Δ)-3>²⁺ <(S or R)-PhEtbpy = 4,4'-bis<(S)-(-) or (R)-(+)-1-phenylethylaminocarbonyl>-2,2'-bipyridine> was realized in the helical-shape recognition reaction with a maximum enantiomer rate ratio (k^Δ/k^Λ) of 14.7 in 90percent v/v EtOH-H2O at 25 degC.

Full text of DOI:10.1039/c39930001423

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(ethylenediaminetetraacetato)cobalt(II)^(2-)

Cas No:110169-72-7

R&D Labs maybe for 110169-72-7

Skyrun Industrial Co.,Ltd(expird)

website:http://www.chinaskyrun.com

Contact:0086-576-84610586

Address:Chemical Development Zone
Nanjing Habo Medical Technology Co., Ltd.

Contact:025－85769882

Address:No.108. Ganjiabian east. Qixia District .Nanjing
Nanjing yieldpharma co.ltd

Contact:13813902930 025-52714267

Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
Alchemy industrial limited

Contact:+86-18200374913

Address:Hongmei Road, No. 99

Relevant to this article

The adduct formation between the thioguanine-polyamine ligands and DNA with the AP site under UVA irradiated and non-irradiated conditions

Doi:10.1016/j.bmc.2019.115160
(2019)
Doi:10.1139/v68-361
(1968)
Synthesis, activity and mechanism of alkoxy-, carbamato-, sulfonamido-, thioureido-, and ureido-derivatives of 2,4,5-trimethylpyridin-3-ol against inflammatory bowel disease

Doi:10.1080/14756366.2019.1677637
(2020)
Synthesis of Gramicidin S and Its Analogues via an On-Resin Macrolactamization Assisted by a Predisposed Conformation of the Linear Precursors

Doi:10.1021/jo035712x
(2004)
Stability, absorption, excretion, and distribution of nafiverine

Doi:10.1002/jps.2600640212
(1975)
Cyclooctyne [60]fullerene hexakis adducts: A globular scaffold for copper-free click chemistry

Doi:10.1039/c6cc05484f
(2016)

Article Doi