Pd(0)-catalyzed hydrogenolysis of allylic and dienylic cyclic carbonates: Synthesis of optically active homoallylic alcohols and allylic alcohols

Article abstract of DOI:10.1080/00397919508010808

Treatment of chiral allylic cyclic carbonates with ammonium formate in the presence of Pd(0) catalyst afforded optically active homoallylic alcohols with excellent regioselectivity. However, hydrogenolysis of dienylic cyclic carbonates in the presence of

Full text of DOI:10.1080/00397919508010808

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Synthetic Communications: An
International Journal for Rapid
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Organic Chemistry
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Pd(0)-Catalyzed Hydrogenolysis
of Allylic and Dienylic Cyclic
Carbonates: Synthesis of
Optically Active Homoallylic
Alcohols and Allylic Alcohols
a
a
a
Suk-Ku Kang , Dong-Chul Park , Ho-Sik Rho
,
a
a b
Chan-Mo Yu & Jang-Hoo Hong
a
Department of Chemistry , Sung Kyun Kwan
University , Natural Science Campus, Suwon,
4
40-746, Korea
b
Department of Fine Chemistry , Seoul National
Polytechnic University , Seoul, 139-743, Korea
Published online: 23 Sep 2006.
To cite this article: Suk-Ku Kang , Dong-Chul Park , Ho-Sik Rho , Chan-Mo Yu &
Jang-Hoo Hong (1995) Pd(0)-Catalyzed Hydrogenolysis of Allylic and Dienylic Cyclic
Carbonates: Synthesis of Optically Active Homoallylic Alcohols and Allylic Alcohols,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 25:2, 203-214, DOI: 10.1080/00397919508010808
To link to this article: http://dx.doi.org/10.1080/00397919508010808
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