PREPARATION OF UNSTABLE 3-ALKYLIDENE FURANS BY THE PALLADIUM-CATALYZED REACTION OF α-ALKYNYL EPOXIDES WITH β-KETO ESTERS

DOI: 10.1016/S0040-4039(00)95798-8

Source and publish data:

Tetrahedron Letters p. 629 - 632 (1987)

Update date:2022-08-12

Topics:

Authors:

Minami, Ichiro

Yuhara, Masami

Tsuji, Jiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95798-8

Palladium-catalyzed reaction of α-alkynyl epoxides with β-keto esters gives unstable 3-alkylidene-2,3-dihydrofuran-4-carboxylates.It can be carried out under mild neutral conditions, and offers a good preparative method for 3-alkylidene furans.

Full text of DOI:10.1016/S0040-4039(00)95798-8

Products guided by the article

Product name:3-Furancarboxylic acid, 4,5-dihydro-5-(hydroxymethyl)-2,5-dimethyl-4-(phenylmethylene)-, methyl ester, (E)-

Cas No:110410-96-3

R&D Labs maybe for 110410-96-3

TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
Guangzhou Flower's Song Fine Chemical CO,. Ltd

Contact:+86-20-87475199

Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China
Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Weifang Jahwa Chemical Co.,Ltd

Contact:0086-536-8897731,8897730

Address:No.5166 East Dongfeng Street,Weifang,Shandong,China

Relevant to this article

Zirconyl Nitrate as an Efficient Catalyst for Facile Synthesis of 2-Aryl-2,3-dihydroquinolin-4(1 H)-one Derivatives in Aqueous Medium

Doi:10.1055/s-0036-1589110
(2018)
ADMET Polymers Containing Precisely Spaced Pendant Boronic Acids and Esters

Doi:10.1021/acs.macromol.5b01410
(2015)
Regulated assemblies and anion responsive vesicles based on 1,3-alternate oxacalix[2]arene[2]triazene amphiphiles

Doi:10.1039/c4cc05924g
(2014)
Improved synthesis of 1,3-diaza-6-adamantanone

Doi:10.1080/00304940309355865
(2003)
Synthesis and characterization of the anticancer and metal binding properties of novel pyrimidinylhydrazone derivatives

Doi:10.1016/j.jinorgbio.2014.12.015
(2015)
Titania Morphology-Dependent Gold-Titania Interaction, Structure, and Catalytic Performance of Gold/Titania Catalysts

Doi:10.1002/cctc.201500599
(2015)

Article Doi