Journal of Organic Chemistry p. 5057 - 5059 (1987)
Update date:2022-08-11
Topics:
Wu, Tse-Chong
Wehmeyer, Richard M.
Rieke, Reuben D.
Reactions of epoxides with some unusually functionalized organocopper compounds generated from direct addition of zerovalent copper to organic halides are described.Organocopper reagents containing esters, nitriles, chlorides, and epoxides have been prepared.The first intramolecular cyclization via an epoxide cleavage process using the activated copper is also described.
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