Tetrahedron Letters p. 5231 - 5234 (1989)
Update date:2022-08-11
Topics:
Shelnutt, J.A.
Trudell, D.E.
Photochemical oxidation of hydrocarbons using molecular oxigen as oxidant and Sn(IV)-or Sb(V)-porphyrin as photosensitizer to generate the required co-reductant is described.Fe(III)-or Mn(III)-porphyrin is the hydrocarbon-oxidation catalyst.The system is long-lived and may be used in photo-initiated spectroscopic kinetic studies.
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