PHOTOCHEMICALLY-DRIVEN BIOMIMETIC OXIDATION OF ALKANES AND OLEFINES

DOI: 10.1016/S0040-4039(01)93749-9

Source and publish data:

Tetrahedron Letters p. 5231 - 5234 (1989)

Update date:2022-08-11

Topics:

Authors:

Shelnutt, J.A.

Trudell, D.E.

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Article abstract of DOI:10.1016/S0040-4039(01)93749-9

Photochemical oxidation of hydrocarbons using molecular oxigen as oxidant and Sn(IV)-or Sb(V)-porphyrin as photosensitizer to generate the required co-reductant is described.Fe(III)-or Mn(III)-porphyrin is the hydrocarbon-oxidation catalyst.The system is long-lived and may be used in photo-initiated spectroscopic kinetic studies.

Full text of DOI:10.1016/S0040-4039(01)93749-9

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