Chemistry of Heterocyclic Compounds p. 243 - 246 (1986)
Update date:2022-08-17
Topics:
Karakhanov, E. A.
Neimerovets, E. B.
Pshezhetskii, V. S.
Dedov, A. G.
The catalytic hydrogenation of furfural with molecular hydrogen has been investigated under mild conditions in the presence of metal complex catalysts with a polymeric macroligand.It has been shown that the reaction proceeds according to a consecutive scheme with the formation of furfuryl and tetrahydrofurfuryl alcohols.The kinetics of furfural hydrogenation has been investigated and the order of the reaction established; the rate constants of the first and second stages have been determined.The influence of the solvent and of the metal-to-polymer ratio on the furfural conversion have been investigated.
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