High Molecular Weight Hydrocarbons from the Fischer-Tropsch Process with a Pre-oxidized Ruthenium Zeolite Catalyst

DOI: 10.1039/c39840000626

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 626 - 628 (1984)

Update date:2022-08-16

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Authors:

Audier, Marc

Klinowski, Jacek

Benfield, Robert E.

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Article abstract of DOI:10.1039/c39840000626

The catalytic performance of zeolite-based ruthenium catalysts in the Fischer-Tropsch reaction depends on the sequence of oxidations/reductions to which they are subjected: with finely divided Ru particles obtained by reducing 3+-exchanged synthetic faujasitic zeolite, methane is the predominant product; but when the zeolite is first oxidised in air at 400 deg C forming crystallites of RuO2 which can then be reduced, longer-chain hydrocarbons are produced at low reaction temperatures (155 deg C).

Full text of DOI:10.1039/c39840000626

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