Tetrahedron p. 2585 - 2590 (1982)
Update date:2022-08-10
Topics:
Sergeev, G. B.
Stepanov, N. F.
Leenson, I. A.
Smirnov, V. V.
Pupyshev, V. I.
et al.
Experimental results on the products and the kinetics of the hydrogen bromide addition to alkenes-1 in non-polar solvents and on complex formation in hydrogen bromide-olefin-solvent systems are reviewed.Theoretical calculations concerning hydrogen bromide-olefin complexes are used along with the experimental evidence to suggest a molecular mechanism of addition involving intermediate cyclic structures.
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