α-Deuterium and Carbon-13 Kinetic Isotope Effects Associated with the SN2 Displacement of Iodide and Tosylate by Lithium Organocuprates

DOI: 10.1021/ja00307a032

Source and publish data:

Journal of the American Chemical Society p. 6028 - 6030 (1985)

Update date:2022-08-16

Topics:

Authors:

Guo, Cong-yuan

Brownawell, Marilyn L.

Filippo, Joseph San, Jr.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00307a032

The secondary α-deuterium and 13C isotope effects associated with the competitive methylation of two cuprates, (n-C8H17)2CuLi(PBu3) and (n-C8H17)4CuLi3(PBu3), by CH3X-CD3X and 12,13CH3X (X=I or OTs) together with their related temperature dependences are reported.

Full text of DOI:10.1021/ja00307a032

Products guided by the article

Product name:n-Nonane

Cas No:111-84-2

R&D Labs maybe for 111-84-2

Rugao Jinling Chemical Co., Ltd.(expird)

Contact:0086-513-68005586

Address:Lianluo new village huangshi town Rugao city Jiangsu Province.
Shao Xing Empire Import&Export CO.,ltd

Contact:86-575-82127757

Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)

Contact:+86-571-87046953

Address:No. 37, Qingchun Road
HANGZHOU ICH BIOFARM CO.,LTD

Contact:+86-571-28186845

Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China

Relevant to this article

Mechanistic Definition of Trimethylstannylation of 1,3-Dihaloadamantanes: Delocalized Radical Anions as Possible Intermediates

Doi:10.1021/jo00078a009
(1993)
Synthesis and antiproliferative properties of a photoactivatable analogue of ET-18-OCH₃

Doi:10.1016/S0040-4020(01)00901-2
(2001)
Specific heat of α′-NaV₂O₅ at its spin-Peierls transition

Doi:10.1103/PhysRevB.58.R2937
(1998)
5,8-DIHYDROXY-7-METHOXYFLAVONE FROM THE IMMATURE LEAVES OF DIDYMOCARPUS PEDICELLATA

Doi:10.1016/0031-9422(92)83162-R
(1992)
Stabilization of Carboxylate Anion with a NH...O Hydrogen Bond: Facilitation of the Deprotonation of Carboxylic Acid by the Neighboring Amide NH Groups

Doi:10.1246/bcsj.77.321
(2004)
The structure of glibenclamide in the solid state

Doi:10.1002/mrc.2868
(2012)

Article Doi