α-Deuterium and Carbon-13 Kinetic Isotope Effects Associated with the SN2 Displacement of Iodide and Tosylate by Lithium Organocuprates

DOI: 10.1021/ja00307a032

Source and publish data:

Journal of the American Chemical Society p. 6028 - 6030 (1985)

Update date:2022-08-16

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Authors:

Guo, Cong-yuan

Brownawell, Marilyn L.

Filippo, Joseph San, Jr.

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Article abstract of DOI:10.1021/ja00307a032

The secondary α-deuterium and 13C isotope effects associated with the competitive methylation of two cuprates, (n-C8H17)2CuLi(PBu3) and (n-C8H17)4CuLi3(PBu3), by CH3X-CD3X and 12,13CH3X (X=I or OTs) together with their related temperature dependences are reported.

Full text of DOI:10.1021/ja00307a032

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