Synthesis, Crystal Structure and Chemical Reactivity of Dichloro(thiosemicarbazide)copper(II)

DOI: 10.1039/DT9910002121

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2121 - 2124 (1991)

Update date:2022-08-28

Topics:

Authors:

Chattopadhyay, D.

Majumdar, S. K.

Lowe, P.

Schwalbe, C. H.

Chattopadhyay, S. K.

Ghosh, S.

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Article abstract of DOI:10.1039/DT9910002121

The structure of dichloro(thiosemicarbazide)copper(II), , has been determined by X-ray crystallography.Contrary to earlier proposals the compound is found to be monomeric.Electron spin resonance studies of the compound both as a polycrystalline solid and in dimethylformamide solution are also in accordance with a monomeric structure.The reactivity of towards some Lewis bases such as imidazole, 2,2'-bipyridyl etc. has also been studied.

Full text of DOI:10.1039/DT9910002121

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