REACTIONS OF VINYLSILANES WITH ETHOXYCARBONYLNITRENE UNDER PHASE-TRANSFER CONDITIONS; A NOVEL ROUTE TO SILICON-CONTAINING AZIRIDINES

DOI: 10.1016/0022-328X(86)80493-4

Source and publish data:

Journal of Organometallic Chemistry p. 249 - 254 (1986)

Update date:2022-08-10

Topics:

Authors:

Lukevics, E.

Dirnens, V. V.

Goldberg, Yu. Sh.

Liepinsh, E. E.

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Article abstract of DOI:10.1016/0022-328X(86)80493-4

The addition of ethoxycarbonylnitrene, generated from ethyl N-(p-nitrobenzenesulphonyloxy)carbamate under liquid-liquid phase-transfer conditions to vinyl-, α-bromovinyl- and (β-methoxycarbonylvinyl)(trialkyl)silanes affords the corresponding 1-ethoxycarbonyl-2-trialkylsilylaziridines.

Full text of DOI:10.1016/0022-328X(86)80493-4

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