Ein einfaches Verfahren zur Herstellung von Organozinnaziden. Synthese und Struktur der sterisch gehinderten Stannylazide tBu3SnN3 und tBu2Sn(N3)2

Article abstract of DOI:10.1016/0022-328X(95)05420-T

Sterically crowded stannyl azides ^tBunSn(N3)4-n (IIa,b) have been prepared for the first time by the reactions of stannylamines ^tBunSn(NHR)4-n (Ia,b) with Me3SiN3 (a: n = 3, R = H; b: n = 2, R = ^tBu).The novel compounds were characterized by NMR (1H, 13C) and mass spectroscopy and their molecular structure determined by X-ray crystallography (IIa: space group P2₁/m, Z = 2; IIb: space group P2₁/n, Z = 4). Keywords: Tin; Stannyl azides; Synthesis; X-ray structure