Synthesis and catalytic activity of a fluorous-tagged TEMPO radical

DOI: 10.1016/j.tetlet.2004.04.021

Source and publish data:

Tetrahedron Letters p. 4249 - 4251 (2004)

Update date:2022-08-11

Topics:

Authors:

Pozzi, Gianluca

Cavazzini, Marco

Holczknecht, Orsolya

Quici, Silvio

Shepperson, Ian

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Article abstract of DOI:10.1016/j.tetlet.2004.04.021

A fluorous-tagged TEMPO radical has been prepared and its catalytic activity in the chemoselective oxidation of alcohols to carbonyl compounds has been investigated. The new fluorous radical proved to be an efficient, selective and easily recoverable catalyst, which can be conveniently used in standard organic solvents and then isolated and recycled by fluorous liquid-liquid extraction.

Full text of DOI:10.1016/j.tetlet.2004.04.021

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