Journal of Organometallic Chemistry p. 365 - 372 (1990)
Update date:2022-08-28
Topics:
Julia, Marc
Lauron, Helene
Verpeaux, Jean-Noel
Three reactions of the cyclopentadienyl(phosphine)(α-benzenesulfonylalkyl)nickel complexes have been investigated: (i) oxidation with oxygen is shown to provide a new and efficient method of preparing aldehydes from sulfones; (ii) treatment with strong Lewis acids gives the corresponding terminal alkenes (the mechanism is briefly discussed); (iii) deprotonation by strong bases gives an anionic species which can in turn be alkylated by iodomethane.
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Doi:10.1007/BF00897773
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