Tetrahedron Letters p. 5391 - 5394 (1982)
Update date:2022-08-17
Topics:
Adam, Waldemar
Oppenlaender, Thomas
The 185-nm denitrogenation of 2,3-diazabicyclo<2.2.1>heptene (1) afforded bicyclo<2.1.0> pentane (2) and cyclopentene (3) presumably via a "hot" cyclopentane-1,3-diyl diradical (8); 1,4-pentadiene (4) and methylenecyclobutane (5) were secondary products of the 185-nm photolysis of (2) and (3).
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