Journal of Organometallic Chemistry p. 113 - 116 (1982)
Update date:2022-08-11
Topics:
Larson, Gerald L.
Cadiz, Carlos
Attempts to generate chlorocarbene or bromocarbene from (dichloromethyl)trimethylsilane and (dibromomethyl)trimethylsilane, respectively, under phase transfer conditions results in protodesilylation.The protodesilylation of 1,1-dihalosilanes under phase transfer conditions appears to be general.Phase transfer conditions are also useful for the protodesilylation of other organosilanes.
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