Organic Letters
Letter
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7) The allenylphosphine oxides such as 1a were synthesized
(
according to the Horner-Mark rearrangement procedure from
propargylic alcohols and diphenylphosphine chloride, but note that
this procedure under an oxygen atmosphere did not give
alkynylphosphinates (2) as major products generally. See refs 6a−d
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direct phosphorylation of tertiary propargylic alcohols with
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9) CCDC (1875348) (2b) contains the supplementary crystallo-
graphic data for this paper. These data can be obtained free of charge
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Org. Lett. XXXX, XXX, XXX−XXX