Tetrahedron p. 4991 - 5004 (1998)
Update date:2022-08-16
Topics:
Starmans, Wim A. J.
Walgers, Richard W.A.
Thijs, Lambertus
De Gelder, Rene
Smits, Jan M.M.
Zwanenburg, Binne
The preparation of a new class of azetidine-based auxiliaries and their selectivity in the BBr3 catalyzed Diels-Alder reaction is described. The results are compared with a similar proline-derived ligand and a known prolinol auxiliary. Results show that selectivities are highly dependent on the dienophile and the substituent of the chiral auxiliary.
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