Tetrahedron Letters p. 31 - 34 (1995)
Update date:2022-08-24
Topics:
Andrew Evans, P.
Roseman, Jamine D.
Treatment of the acyl selenide 7 with triphenyltin hydride and triethylborane generates the acyl radical which undergoes 5-exo trigonal cyclization to afford the 2,5-disubstituted tetrahydrofuran-3-ones 10a/b in 97percent yield as a 94:6 mixture of diastereoisomers.
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