Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry p. 519 - 531 (2003)
Update date:2022-08-04
Topics:
Manhas
Sardana
Kalia
New copper(II) toluate complexes with saturated monoheterocyclic bases, substituted piperidines, of the type Cu(OOCR)2L (where R = 2-, 3-, or 4-CH3C6H4 and L = 1-methyl-, 1-ethyl- or 2,6-dimethylpiperidine) have been synthesized and characterized by elemental analyses, IR, electronic reflectance and EPR spectral and magnetic susceptibility measurement studies. All of these complexes show antiferromagnetic behaviour. The spin exchange parameter, - 2J, for three of these complexes has been evaluated from EPR measurements at different temperatures, which corresponds to axial binuclear copper(II) complexes with S = 1.
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