ELECTRONIC EFFECTS IN THE SEMICONDUCTOR - PHOTOCATALYZED OXIDATIVE CLEAVAGE OF OLEFINS

Article abstract of DOI:10.1016/S0040-4039(00)81460-4

A linear Hammett plot (p⁺=-0.56) is obtained from relative rates of TiO2 powder sensitized oxidative cleavage of para-substituted 1,1-diphenylethylenes, better correlation having been observed with ?⁺ parameters than with ?.