Chemistry Letters p. 1945 - 1948 (1993)
Update date:2022-08-17
Topics:
Kunai, Atsutaka
Kawakami, Toshihiro
Toyoda, Eiji
Sakurai, Tomohiro
Ishikawa, Mitsuo
Electrolytic oxidation of dimethylphenylsilane (1) in the presence of CuCl2 or CuCl afforded chlorodimethylphenylsilane in high yields (>90percent), while similar electrolysis of 1 in the presence of BF4- ions afforded fluorodimethylphenylsilane in 90percent yield. 1,2-Diphenyltetramethyldisilane was obtained from 1 in 48percent yield by the electrolysis with a Pt-Cu electrode system.A "paired" electrolysis of methyldiphenylsilane on the anode and chloromethyldiphenylsilane on the cathode afforded 1,2-dimethyltetraphenyldisilane in 64percent yield.
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