Influence of Pore Confinement on the Catalytic Dehydration of Isobutyl Alcohol on H-ZSM-5

DOI: 10.1039/ft9908600581

Source and publish data:

Journal of the Chemical Society - Faraday Transactions p. 581 - 584 (1990)

Update date:2022-08-11

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Authors:

Makarova, M. A.

Williams, C.

Romannikov, V. N.

Zamaraev, K. I.

Thomas, J. M.

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Article abstract of DOI:10.1039/ft9908600581

The dehydration of isobutyl alcohol has been used as a test to probe the differences in catalytic behaviour between an (acidic) amorphous aluminosilicate and samples of H-ZSM-5 of various crystallite size but of similar acidity (+> ca. 3E20 g_-1) as the amorphous aluminosilicate.Dehydration rates are shown to be independent of crystallite size (in the range 0.5-20 μm), but rates of oligomerization of the product butene are higher for the large crystallites.

Full text of DOI:10.1039/ft9908600581

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