THE MOLECULAR COMPONENT IN THE THERMAL DECOMPOSITIN OF AZOMETHANE

DOI: 10.1039/f19837901891

Source and publish data:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1891 - 1900 (1983)

Update date:2022-08-17

Topics:

Authors:

Marshall, Roger M.

Shahkar, Gholamreza

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Article abstract of DOI:10.1039/f19837901891

The pyrolysis of isobutane sensitised by <1.5percent of azomethane has been investigated over the ranges 504-640 K and 40-300 Torr in reactors of differing surface/volume ratio and surface treatment.The previously suggested molecular component of the decomposition has been confirmed and shown to be a heterogeneous process.A small number of experiments at 577 K in which isobutane was replaced successively by propane, cyclopropane and chloroform gave essentially identical results for the molecular decomposition.Conditions in which azomethane can be used in a conventional investigation of the reactions of methyl radicals are discussed.

Full text of DOI:10.1039/f19837901891

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