Linear relationship of the rate of isobutene formation from CO and H2 on ZrO2 to the monoclinic phase fraction

DOI: 10.1246/cl.1999.575

Source and publish data:

Chemistry Letters p. 575 - 576 (1999)

Update date:2022-08-11

Topics:

Authors:

Maruya, Ken-Ichi

Komiya, Teruaki

Okumura, Koichiro

Yashima, Masatomo

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Article abstract of DOI:10.1246/cl.1999.575

The rate of formation of isobutene from CO and H₂ over ZrO₂ is proportional to the volume fraction of the monoclinic phase. The active site was explained by both vacant site and stronger bascity due to the shorter Zr-O bond in the monoclinic structure.

Full text of DOI:10.1246/cl.1999.575

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