Journal of the Chemical Society. Chemical communications p. 456 - 458 (1991)
Update date:2022-08-11
Topics:
Buerger, Hans
Sommer, Silvia
Difluoroethyne, FC<*>CF 1, has been prepared by vacuum pyrolysis of perfluoro-1,2,3-triazine, isolated in pure form and characterized by 19F NMR and gas phase IR spectroscopy; its decomposition, with a half-life-time at 300 K and ca. 2.5 mbar of ca. 15 min, yields in the first step a polymer and :CF2, the latter either oligomerizing or reacting with 1 to form three different C3F4 isomers.
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