
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 503 - 511 (1980)
Update date:2022-08-17
Topics:
Stock, Colin J.
Whittle, Eric
The photolysis of the vapour of perfluorosuccinic anhydride was studied at 22 and 199 deg C.The effective primary process is (C2F2O)2O+hυ -> CO+CO2+C2F4.The quantum yields of products are little affected by change of pressure but they decrease on increasing the pressure of anhydride or of added perfluoromethylcyclohexane.The results are compared with those for related fluoroanhydrides.
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