Photodecomposition of 1,2-difluoro-1,2-di-iodoethene: formation of 1,2-difluoroethyne

DOI: 10.1016/S0022-1139(00)80473-X

Source and publish data:

Journal of Fluorine Chemistry p. 53 - 58 (1993)

Update date:2022-08-29

Topics:

Authors:

Friedrich, H. B.

Tardy, D. C.

Burton, D. J.

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Article abstract of DOI:10.1016/S0022-1139(00)80473-X

Photolysis of trans-1,2-difluoro-1,2-di-iodoethene with 248 nm radiation from an excimer laser yielded difluoroethyne, cis-1,2-difluoro-1,2-di-iodoethene and 1,2,3,4,-tetrafluoro-3,4-di-iodocyclobutene.Potential pathways for these products are presented in terms of the energetics of the reaction, and the dependencies of product formation on pressure and extent of conversion are discussed.

Full text of DOI:10.1016/S0022-1139(00)80473-X

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