
Russian Chemical Bulletin p. 45 - 49 (1999)
Update date:2022-08-12
Topics:
Kuricheva
Dunyakhin
Timofeev
Zhitnev
The mechanism of oxidation of C3F6 by molecular O2 under IR multiphoton excitation was studied. The activation energy of C3F6 oxidation was estimated from the dependence of the reagent conversion on the O2 pressure. The data obtained for the final reaction products, CF3CFO and CF2O, suggest the dioxetane mechanism of C3F6 oxidation.
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