The reaction of C3F6 with dioxygen under IR laser initiation

DOI: 10.1007/BF02494398

Source and publish data:

Russian Chemical Bulletin p. 45 - 49 (1999)

Update date:2022-08-12

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Authors:

Kuricheva

Dunyakhin

Timofeev

Zhitnev Zhitnev

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Article abstract of DOI:10.1007/BF02494398

The mechanism of oxidation of C₃F₆ by molecular O₂ under IR multiphoton excitation was studied. The activation energy of C₃F₆ oxidation was estimated from the dependence of the reagent conversion on the O₂ pressure. The data obtained for the final reaction products, CF₃CFO and CF₂O, suggest the dioxetane mechanism of C₃F₆ oxidation.

Full text of DOI:10.1007/BF02494398

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