
Tetrahedron p. 1427 - 1430 (1974)
Update date:2022-08-17
Topics:
Greaves
Landor
Landor
Odyek
Allenic amides are prepared from allenic nitriles using alkaline hydrogen peroxide and by a Ritter reaction with t-butyl alcohol, when N-t-butylamides are obtained. Strong nucleophiles attack the central carbon of the allene system to give α,β-unsaturated addition products.
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(1996)