Tetrahedron p. 5139 - 5146 (1994)
Update date:2022-08-11
Topics:
Bachki, Abderrazak
Foubelo, Francisco
Yus, Miguel
The reaction of differnt aromatic compounds 1a-1t with iodine and a mercury(II)-salt 2 [mercury(II) chloride, nitrate or triflate] (1:1:1 molar ratio) in dichloromethane at room temperature leads to the corresponding iodoarene 3, the obtained regiochemistry being the expected. Concerning the mercury(II) salt, the observed reactivity decreased in the series triflate > nitrate > chloride according to their ionic character. An activation of the iodine molecule by the mercury(II) salt followed by a S(E) reaction with the aromatic compounds is postulated as the possible mechanism.
View More
Contact:13864437655
Address:Zibo city, shandong province Zhang Dian award and industrial park HaiDing chemical plant
Golden Union Agrochemical Import and Export Co., Ltd.
Contact:86-755-23910527
Address:Room 1106, Tower 3A, Excellence Century Center, Futian District, Shenzhen, China
Hangzhou innopharma technology Co,.Ltd.(expird)
Contact:+86-13388601988
Address:Room845,lixin building, moganshan road, hangzhou, china
Shanghai Massive Chemical Technology Co., Ltd.
website:http://www.massivechem.com/
Contact:+86 21 34943721
Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
SEA BRGIHT INDUSTRY CO.,LIMITED
Contact:0086 755 8622 3990
Address:Rm 17B3,GuangCaiXinTianDi Bldg,GuiMiao Rd,NanShan District,Shenzhen,China
Doi:10.1007/s10973-010-0760-6
(2010)Doi:10.1021/acs.orglett.6b00169
(2016)Doi:10.1016/j.bmc.2016.05.068
(2016)Doi:10.1016/j.foodchem.2015.05.089
(2016)Doi:10.1016/0957-4166(95)00022-H
(1995)Doi:10.1002/jccs.200700147
(2007)
