Electropolymerization of cobalto(5,10,15-tris(4-aminophenyl)-20-phenylporphyrin) for electrochemical detection of antioxidant-antipyrine

Article abstract of DOI:10.1142/S1088424615500443

Porphyrins are a kind of aromatic molecules possessing unique physic-chemical properties. In this manuscript, it was thus utilized to synthesize 5,10,15-tris(4-aminophenyl)-20-phenylporphyrin and cobalto(5,10,15-tris(4-aminophenyl)-20-phenylporphyrin). In addition, conducting cobalto(5,10,15-tris(4-aminophenyl)-20-phenylporphyrin) polymeric films were successfully prepared by electropolymerization approach on glassy carbon electrode in the presence of dimethyl formamide solution and 0.1 M tetra-n-butyl ammonium perchlorate at 100 mV/s scan rate. The synthesized polymeric films were evaluated as the active electrode materials to detect an antioxidant (Antipyrine) present in pharmaceuticals and the limit of detection is ～74 μM.