Tetrahedron Letters p. 2867 - 2870 (1995)
Update date:2022-08-16
Topics:
Costa, Mirco
Mor, Andrea
A new catalytic synthesis of substituted cyclopentenones from alkynes, alkenes bearing an electron-withdrawing group and CO in the presence of Co2(CO)8 is reported.It consists of a coupled process involving Pauson-Khand and Michael-type reactions.The formation of cyclopentenone derivatives is strongly dependent on the nature of the alkyne and of the activated alkene.
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