Electronic Control of the Co-ordination Mode of an Alkyne to a Trimetallic Cluster; X-ray Crystal Structure of Os3(CO)7(μ3-η2()-PhCCPh)(Ph2PCH2PPh2)

DOI: 10.1039/c39870001829

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1829 - 1831 (1987)

Update date:2022-08-11

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Authors:

Clucas, Jennifer A.

Dolby, P. Ann

Harding, Marjorie M.

Smith, Anthony

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Article abstract of DOI:10.1039/c39870001829

Treatment of the unsaturated triosmium cluster Os3(μ-H)(CO)8<μ-Ph2CH2P(Ph)C6H4> with diphenylacetylene leads to the formation of Os3(CO)7(PhC<*>CPh)(Ph2PCH2PPh2), in which the alkyne ligand is bonded in a μ₃-η₂(<*>) mode, as shown by an X-ray crystal structure determination.

Full text of DOI:10.1039/c39870001829

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