Journal of the Chemical Society. Chemical communications p. 1829 - 1831 (1987)
Update date:2022-08-11
Topics:
Clucas, Jennifer A.
Dolby, P. Ann
Harding, Marjorie M.
Smith, Anthony
Treatment of the unsaturated triosmium cluster Os3(μ-H)(CO)8<μ-Ph2CH2P(Ph)C6H4> with diphenylacetylene leads to the formation of Os3(CO)7(PhC<*>CPh)(Ph2PCH2PPh2), in which the alkyne ligand is bonded in a μ3-η2(<*>) mode, as shown by an X-ray crystal structure determination.
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Doi:10.1007/BF02144361
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