Chemistry Letters p. 831 - 834 (1983)
Update date:2022-08-28
Topics:
Ueno, Yoshio
Yadav, L. D. S.
Okawara, Makoto
2-(Phenacylthio)benzothiazole (1) reacted with aldehyde or ketone in the presence of tri-n-butylphosphine at 80 deg C to give α,β-enone and 2-mercaptobenzothiazole in good yield.The reaction scheme for this new type of enolate ion formation via C-S bond cleavage is also described.
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