Studies on the Aminopyrimidinyl Group of Thiamine

DOI: 10.1039/c39850001551

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1551 - 1553 (1985)

Update date:2022-08-17

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Authors:

Doughty, Michael B.

Risinger, G. E.

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Article abstract of DOI:10.1039/c39850001551

Although 3-(4-amino-2-methyl-pyrimidin-5-yl)methyl-5-ethoxycarbonyl-4-methylthiazolium chloride (2) undergoes a rapid C-2 H/D exchange in acidic D2O, formation of its neutral tricyclic form in basic solution completely inhibits the ability of this thiamine analogue to catalyse the benzoin condensation.

Full text of DOI:10.1039/c39850001551

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