Pyridinium dichromate-assisted oxidative cleavage of α-functionalized benzylic alcohols by sodium percarbonate under phase-transfer conditions

Article abstract of DOI:10.1080/00397919508015886

The course and the efficacy of the oxidation by sodium percarbonate of benzylic alcohols, α-substituted by a keto, hydroxy, ester or acid group, are dependent on the nature of both α-group and the solvent, and yields are usually improved by the presence of catalytic amounts of Cr(VI) species. The oxidative cleavage of the C(OH)-C(α) bond is the main process observed.

Full text of DOI:10.1080/00397919508015886

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Synthetic Communications: An
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Pyridinium Dichromate-
Assisted Oxidative Cleavage
of α-Functionalized
Benzylic Alcohols by Sodium
Percarbonate Under Phase-
Transfer Conditions
Samia Aït Mohand a , Aviava Levina a & Jacques
Muzart a
a Unité “Réarrangements Thermiques et
Photochimiques” Associée au CNRS Université de
Reims Champagne-Ardenne , B.P. 347, 51062, Reims
Cedex, France
Published online: 23 Sep 2006.
To cite this article: Samia Aït Mohand , Aviava Levina & Jacques Muzart (1995)
Pyridinium Dichromate-Assisted Oxidative Cleavage of α-Functionalized Benzylic
Alcohols by Sodium Percarbonate Under Phase-Transfer Conditions, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 25:14, 2051-2059, DOI: 10.1080/00397919508015886
To link to this article: http://dx.doi.org/10.1080/00397919508015886
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