Tetrahedron Letters p. 9055 - 9056 (1997)
Update date:2022-08-16
Topics:
Kovacs, Gabor
Micskei, Karoly
Stoichiometrically controlled reductive epoxidation could be elaborated to transform α,β-diketones or α-hydroxy ketones to epoxides in a very good yields in neutral aqueous medium using chromium(II)acetate. Modification of the coordination sphere of Cr(II) ion with the added ligand makes the reductive ring-opening possible.
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