S,S-dimethyl dithiocarbonate: A novel carbonyl dication synthon in the synthesis of ketones

DOI: 10.1016/S0040-4020(98)00544-4

Source and publish data:

Tetrahedron p. 9067 - 9078 (1998)

Update date:2022-08-11

Topics:

Authors:

Chen, Chiar-Dy

Huang, Jui-Wen

Leung, Man-Kit

Li, Huei-Hsu

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Article abstract of DOI:10.1016/S0040-4020(98)00544-4

We report herein the use of DMDTC as an effective carbonyl dication equivalent in ketone synthesis. According to our strategy, we also successfully devised a synthetic pathway for S-methyl (trimethylsilyl)thioacetate which may be a potentially useful synthetic reagent in organic synthesis.

Full text of DOI:10.1016/S0040-4020(98)00544-4

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