Journal of Organic Chemistry p. 7138 - 7142 (1993)
Update date:2022-08-11
Topics:
Tanner, Dennis D.
Xie, Guo-Jian
Hooz, John
Yang, Chi-Ming
The reduction of a number of mechanistic probes with several borate complexes, NaBH4, Li(C2H5)3BH, and lithium dimesityl borohydride, has been shown to occur by both an electron transfer-hydrogen atom abstraction mechanism and a hydride transfer process.Although the electron transfer-hydrogen atom abstraction mechanism can nearly always be detected or be initiated, it is usually only a minor reaction, and only when the reducing agent and/or the substrate is sterically hindered or when the acceptor is a strong oxidizing agent is the homolytic pathway preferred.
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