Tetrahedron Letters p. 3937 - 3940 (1988)
Update date:2022-07-29
Topics:
Montarby, Lucy de
Mosset, Paul
Gree, Rene
The chiral iron tricarbonyl complex of sorbic acid 2 is an efficent resolving agent for allylic alcohol 3, which is a key intermediate in the preparation of most of the lipoxygenation products in n-6 position of polyunsaturated fatty acids.The synthesis of 4-hydroxy nonenal and methyl coriolate, in both enantiomeric forms, illustrates the potential of the method.
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