Vinylcyclopropylacyl Radicals. Intramolecular Ketene Additions leading to Concise Syntheses of Cyclohexenones

DOI: 10.1055/s-1997-708

Source and publish data:

Synlett p. 69 - 70 (1997)

Update date:2022-08-16

Topics:

Authors:

Herbert, Nicola

Pattenden, Gerald

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Article abstract of DOI:10.1055/s-1997-708

Treatment of a range of vinylcyclopropyl selenyl esters with Bu₃SnH-AIBN produces cyclohexenone products (50-60%) via 6-exo-dig radical cyclisations involving ketene intermediates.

Full text of DOI:10.1055/s-1997-708

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