A High Activity Molybdenum containing Epoxidation Catalyst and its Use in Regioselective Epoxidation of Polybutadiene

DOI: 10.1039/c39890001688

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1688 - 1690 (1989)

Update date:2022-08-16

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Authors:

Gahagan, Michael

Iraqi, Ahmed

Cupertino, Domenico C.

Mackie, Raymond K.

Cole-Hamilton, David J.

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Article abstract of DOI:10.1039/c39890001688

MoO2Cl2<3-(diethoxyphosphinyl)camphor> is a highly active catalyst for the epoxidation of alkenes by Bu^tOOH; for polybutadiene containing cis-1,4-, trans-1,4-, and 1,2-polymerised units, very high selectivity to the backbone double bonds is observed.

Full text of DOI:10.1039/c39890001688

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