CHELATION CONTROL ASSOCIATED WITH ORGANOMETALIC ADDITION REACTION IN WATER. THE HIGH STEREOSELECTIVITY OFFERED BY α- AND β-HYDROXYL SUBSTITUENTS OBVIATES THE NEED FOR PROTECTING GROUPS.

DOI: 10.1016/00404-0399(50)1439O-

Source and publish data:

Tetrahedron Letters p. 6863 - 6866 (1995)

Update date:2022-08-04

Topics:

Authors:

Paquette, Leo A.

Mitzel, Thomas M.

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Article abstract of DOI:10.1016/00404-0399(50)1439O-

High stereoselectivities have been observed for indium-promoted allylations of α- and β-hydroxy aldehyes in aqueous media, with strong implication that chelate control can continue to operate in water.

Full text of DOI:10.1016/00404-0399(50)1439O-

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