New Neutral Nickel Dithiolene Complexes derived from 1,3-Dialkylimidazolidine-2,4,5-trithione, showing Remarkable Near-IR Absorption

DOI: 10.1039/c39950000371

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 371 - 372 (1995)

Update date:2022-08-30

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Authors:

Bigoli, Francesco

Deplano, Paola

Devillanova, Francesco A.

Lippolis, Vito

Lukes, Peter J.

et al. et al.

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Article abstract of DOI:10.1039/c39950000371

The synthesis, solution redox properties and electronic spectra of a new series of stable, neutral nickel-dithiolene complexes (where R2timdt is the monoreduced anion of the first example of 1,3-dialkylimidazolidine-2,4,5-trithione and alkyl = Et, Prⁱ, Bu), showing an intense electronic absorption at λ ca. 1000 nm, as well as the crystal structure of the Prⁱ derivative are reported.

Full text of DOI:10.1039/c39950000371

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