Reaction of Bidentate Isonitrile Ligands with Iron Carbonyls

DOI: 10.1039/DT9810000297

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 297 - 301 (1981)

Update date:2022-08-30

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Authors:

Howell, James A. S.

Rowan, Anthony J.

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Article abstract of DOI:10.1039/DT9810000297

Reaction of the bidentate isonitriles CN(CH2)nNC ( n =2, 3, 4, or 6) with (cp = η-cyclopentadienyl) yields exclusively <2> derivatives which are fluxional in solution and exist in three isomeric forms (bridged-bridged, bridged-terminal, and terminal-terminal with respect to the bonding mode of the bidentate isonitrile).The proportion of the isomers containing terminally bound isonitrile increases with the length of the alkyl chain.The complexes may be protonated to yield <2>2 salts (n = 2 or 6) and may be cleaved with I2 to give and <2nNC>> (n = 2 or 6).Reaction ofCN(CH2)_nNC (n = 2 or 6 with or yields exclusively <2nNC>>

Full text of DOI:10.1039/DT9810000297

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