
Journal of the Chemical Society, Dalton Transactions p. 1443 - 1447 (1996)
Update date:2022-08-11
Topics:
Yu, Yong
Chen, Jiabi
Chen, Jian
Zheng, Peiju
The reaction of [Mn(≡CPh)(μ-C5H5)(CO)2]BBr4 1 with [NEt4]2[Fe2(CO)8] in tetrahydrofuran at low temperature gave a novel heteronuclear dimetal carbene-bridged complex [MnFe{μ-C(COEt)Ph}(η-C5H5)(CO)5] 3, and a dimetal dicarbene complex [{(OC)2(η-C5H5)Mn(=CPh)}2Fe 2(CO)8] 4, as well as [Mn(η-C5H5)-(CO)3] 2. The same products, 2 and 3, were obtained from the reaction of 1 with Na2[Fe(CO)4]. The structure of 3 has been established by X-ray crystallography.
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