Journal of the American Chemical Society p. 3222 - 3225 (2011)
Update date:2022-08-11
Topics:
Lenhardt, Jeremy M.
Ogle, James W.
Ong, Mitchell T.
Choe, Robert
Martinez, Todd J.
Craig, Stephen L.
Tension along a polymer chain traps neighboring s-trans/s-trans-1,3- diradicals from the mechanically induced ring opening of gem- difluorocyclopropanes (gDFCs). The diradicals correspond to the transition states of the force-free thermal isomerization reactions of gDFCs, and the tension trapping allows a new disproportionation reaction between two simultaneously trapped diradicals to take place.
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