DIOXIRANES: DIMETHYLDIOXIRANE CATALYZED VALENCE ISOMERIZATION OF QUADRICYCLANE

DOI: 10.1016/0040-4039(88)80003-0

Source and publish data:

Tetrahedron Letters p. 15 - 18 (1988)

Update date:2022-08-11

Topics:

Authors:

Murray, Robert W.

Pillay, M. Krishna

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Article abstract of DOI:10.1016/0040-4039(88)80003-0

Dimethyldioxirane, 3, catalyzes the isomerization of quadricyclane to norbornadiene.Turnover numbers up to 60 have been measured.The unusual orbital occupancy in 3 may be responsible for these observations.

Full text of DOI:10.1016/0040-4039(88)80003-0

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