DIOXIRANES: DIMETHYLDIOXIRANE CATALYZED VALENCE ISOMERIZATION OF QUADRICYCLANE

DOI: 10.1016/0040-4039(88)80003-0

Source and publish data:

Tetrahedron Letters p. 15 - 18 (1988)

Update date:2022-08-11

Topics:

Authors:

Murray, Robert W.

Pillay, M. Krishna

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(88)80003-0

Dimethyldioxirane, 3, catalyzes the isomerization of quadricyclane to norbornadiene.Turnover numbers up to 60 have been measured.The unusual orbital occupancy in 3 may be responsible for these observations.

Full text of DOI:10.1016/0040-4039(88)80003-0

Products guided by the article

Product name:2,5-Norbornadiene

Cas No:121-46-0

R&D Labs maybe for 121-46-0

Reliability Assessment Solutions (Changhzou) Co., Ltd.

Contact:86-519-85607515

Address:RM 601-603 BD1 Fuchen Mansion, 8 Taihu East RD, Xinbei District, Changhou, Jiangsu 213022, China
SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China
Shanghai Yudiao Chemistry Technology Co.,Ltd

Contact:0086-18964703211

Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
ShangHai Ruiyi Medical Technology Co.,Ltd.

Contact:+86-21-54718086

Address:No951 Jianchuan RD，Minhang District

Relevant to this article

Doi:10.1021/ja01181a088
(1948)
Facile microwave synthesis of 3D flowerlike BiOBr nanostructures and their excellent Cr^VI removal capacity

Doi:10.1002/ejic.201101427
(2012)
One-step template-free solution route for Cu(OH)₂ nanowires

Doi:10.1134/S0036023608010063
(2008)
Effect of reductants in N₂O reduction over Fe-MFI catalysts

Doi:10.1016/j.jcat.2004.11.009
(2005)
Doi:10.1007/BF00563699
()
Phosphorus pentachloride promoted gem-dichlorination of 2′- and 3′-deoxynucleosides

Doi:10.3390/molecules23061457
(2018)

Article Doi