COBALT(II)TETRAPORPHYRIN-CATALYZED ISOMERISATION OF ELECTRONEGATIVE SUBSTITUTED QADRICYCLANES

DOI: 10.1016/S0040-4039(00)98671-4

Source and publish data:

Tetrahedron Letters p. 3487 - 3490 (1985)

Update date:2022-08-25

Topics:

Authors:

Miki, Sadao

Ohno, Toshinobu

Iwasaki, Hideaki

Yoshida, Zen-ichi

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Article abstract of DOI:10.1016/S0040-4039(00)98671-4

Co(II)TPP-catalyzed isomerisation of a series of electronegative substituted quadricyclanes(1) to the corresponding norbornadiene(2) was found to proceed via radicophilic attack of the metal to 1.

Full text of DOI:10.1016/S0040-4039(00)98671-4

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